Technical Problem-Solving

Fixing Poor Adhesion on Galvanized Steel — Primer & Additive Solutions

Coating adhesion failure on galvanized steel is a significant problem on GCC infrastructure projects — particularly on galvanized structural steel for warehouses, power transmission towers, fencing, and industrial equipment in Saudi Arabia and the UAE. The combination of the passive zinc surface, temperature cycling from 5°C winter nights to 50°C summer days, and the humid coastal environment creates one of the most demanding adhesion challenges in industrial coatings. This guide covers the root causes and the raw material solutions that deliver lasting adhesion.

Why Galvanized Steel is Difficult to Coat

Three main factors cause adhesion problems on galvanized steel:

• Passive zinc surface: The zinc oxide/hydroxide layer on galvanised steel has very low surface energy, making paint wetting and adhesion difficult without surface treatment.
• Zinc soaps: Over time, zinc reacts with free fatty acids in some paint binders (particularly alkyd resins) to form zinc soaps at the interface — leading to saponification and adhesion loss. This is why alkyd paints should never be applied directly over galvanised steel.
• Thermal cycling: Saudi Arabia's daily temperature range of 25–35°C creates significant stress at the coating-zinc interface due to differential thermal expansion, particularly challenging for rigid coating systems.

Surface Preparation — The Foundation of Adhesion

Preparation Method	Standard	Best For	Notes
Sweep (brush) blast cleaning	SSPC-SP16 / ISO 8501-1 BSt 2	New galvanizing before first coating	Creates mechanical anchor profile without removing zinc coating; target 25–40 μm profile
T-wash (mordant solution)	BS 3900 Part C5	Weathered galvanizing; where blast not possible	Phosphoric acid + copper sulfate; converts zinc oxide to zinc phosphate
Solvent wipe	SSPC-SP1	Contamination removal only	Not sufficient alone; always combine with blast or T-wash for coating adhesion
Zinc phosphate pre-treatment	Various	Factory coil-coating or batch galvanizing	Most effective treatment; often done at the galvanizer before delivery to site

Primer Selection for Galvanized Steel

Once the surface is properly prepared, primer selection is critical:

• Two-pack epoxy polyamide (zinc phosphate pigmented): The standard system for galvanised steel in GCC industrial applications. Zinc phosphate pigment provides corrosion inhibition without zinc galvanic protection (which is not needed over galvanized steel). Apply after sweep blast or T-wash. DFT 50–75 μm.
• Etch primer (wash primer): A dilute two-component primer based on polyvinyl butyral resin and phosphoric acid. Applied in a very thin coat (8–15 μm DFT), it chemically etches the zinc surface while providing an adhesion base for subsequent coats. Useful where blast cleaning is not possible on site.
• Two-pack polyurethane primer: Used where maximum flexibility is required, particularly for galvanized steel components subject to flexing or GCC temperature cycling. Provides excellent adhesion and serves as a good base for PU topcoats.

Adhesion Promoter Additives

For formulators seeking to improve adhesion of existing primer systems on galvanized steel:

• Silane coupling agents (amino or epoxy functional): Can be added at 0.5–1.0% to epoxy primers to improve zinc surface adhesion. The silane bonds chemically to the zinc oxide surface while the functional group bonds to the epoxy resin network.
• Zinc phosphate pigment: Replacing standard anticorrosive pigments with zinc phosphate provides mild surface passivation at the zinc/paint interface, improving adhesion stability in humid conditions.
• Adhesion promoter resins (chlorinated polyolefin): Primarily used in automotive coatings over plastics but can be adapted for special galvanized steel applications where maximum adhesion under peel stress is required.

Raw Material Sourcing from Raykem

Raykem supplies epoxy resins, polyamide and polyamidoamine hardeners, and zinc phosphate pigments to paint manufacturers across the UAE and Saudi Arabia. Our solvent range includes Xylene, MEK, and specialty solvents for primer formulation. Contact our technical team for guidance on formulating primers specifically optimised for galvanised steel in GCC conditions.